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Calibration Gas for Product Analysis in Petrochemical Industry
Calibration Gas for Product Analysis in Petrochemical Industry
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RM |
RM No. |
Composition of RM |
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Determination of hydrocarbon impurities in ethylene |
BW(DT0147) |
Calibration gas：methane、ethane、propane、propylene、iso-butane、acetylene、propadiene、n-butane、cis-2-Butene、trans-2-Butene、Isobutylene、、Propyne、1.3-Butadiene in ethylene concentration: 2mg/kg~204mg/kg(4ml/m³~340ml/m³） |
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Determination of hydrocarbon impurities in propylene |
N2 Balance: BW(DT0160) |
Calibration gas：methane, ethane, ethylene, propane, cyclopropane, iso-butane ,n-butane, propadiene, acetylene, trans-2-butene,1-butene, iso-butene, cis-2-butene, 1.3-butadiene,methylacetylene in N2 or propylene balance（N2 balance calibration gas can be used as external calibration; propylene balance calibration gas can be used as calibration area normalization and external calibration） |
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Determination of H2 in ethylene and propylene |
GBW (E) 062158 |
Calibration gas：H2 in ethylene10.0~100（10-6mol/mol） |
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GBW (E) 062159 |
Calibration gas：H2 in propylene 10.0~100（10-6mol/mol） |
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Determination of CO,CO2,acetylenein ethylene or propylene |
N2 balance:BW(DT0159)ethylene balance:BW(DT0147) |
Calibration gas：CO, CO2, acetylene in N2 or ethylene（if determination of impurities in propylene, N2 balance calibration gas shall be used） |
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GBW(E)062240 |
Calibration gas：CO, CO2 in propylene 2.00~100（10-6mol/mol） |
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GBW(E)062241 |
Calibration gas：CO, CO2 in ethylene 2.00~100（10-6mol/mol） |
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Determination of trace sulfide in ethylene or propylene |
BW(DT0130) |
Trace of H2S, COS, MeSH、DMS、DMDS、Ethanethiol、1.1-Thiobisethane、Carbon Disulfide in ethylene/propylene/N2 |
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Determination of oxy-organics in ethylene, propylene |
N2/He balance:BW(DT0106) N-pentane balance:BW(DT0103) |
Calibration gas： ME、DME、MTBE、AD、Ethanol、IPA、Acetone 、MEK in N2/He balance |
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Determination of O2 in ethylene or propylene |
N2 balance：BW(DT0159) |
Calibration gas：Oxygen in N2, ethylene, propylene, or Ar （concentration shall be based on demand） |
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Determination of PH3, AsH3 in ethylene or propylene |
BW(DT0149) |
Calibration gas：PH3, AsH3 in ethylene or propylene 0.1~100（umol/mol） |
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Determination of trace inorganic gases in ethylene or propylene |
Ethylene bal.：BW(DT)0147 |
H2, Ar,O2, N2, CH4, CO, CO2 in ethylene or propylene 1.00~100（umol/mol）。 |
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Determination of oligomer in propylene |
BW(DT1037) |
Calibration liquid（calibration gas）： 3.3-Dimethyl-1-butene、2.3-Dimethyl-1-butene、1.5-Hexadiene、2-Methyl-1-Pentene、1-Hexene、1.4-HEXADIENE、Trans-3-Hexene、2-Hexene、2-Methyl-2-Pentene、2.3-Dimethyl-2-butene、2.4-HEXADIENE、Cyclohexene、1-Nonene、1-Decene in propylene balance （concentration shall be based on demand） |
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Calibration gas for element analysis |
BW(DT)0130 |
Analysis for nitrogen element, chlorine element, sulfide element in He or propylene balance1.00~100mg/kg |
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Purity of ethane |
BW(DT)0151 |
Calibration gas：methane, ethylene, propane, propylene, iso-butane, acetylene, propadiene, n-butane, trans-butene, n-butene, iso-butene, cis-butene、methylacetylene, 1.3-Butadiene in ethane |
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Purity of propane |
N2 bal.：BW(DT)0160 |
Calibration gas：methane, ethane, ethylene, propylene, cyclopropane, iso-butane, n-butane, Propadiene, Acetylene、Trans-2-Butene、1-Butene、Isobutylene、Cis-2-Butene、1.3-Butadiene、Propyne in N2 or propane 2mg/kg~204mg/kg(4ml/m³~340ml/m³） |
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Calibration gas for analysis of major components in coal gas |
BW(DT)0130 |
H2, O2, N2, CO, CO2, methane, ethane, ethylene, propane, propylene, sulfide Typical concentration 0.1-100% |
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Calibration gas for sulfide |
BW(DT)0130 |
H2S、SO2、Carbonyl Sulfide、Methyl Mercaptan、Ethanethiol、Dimethyl Sulfide、1.1-Thiobisethane、DMDS、Thiophene in N2 balance or ethylene, propylene Concentration :1ppm～%。 |
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Calibration gas for refinery plant |
BW(DT)0130 |
Mixture gas of ethane、propane、propylene、cyclopropane、propyne、Propadiene、iso-butane、n-butane、Trans-2-Butene、1-butene、Isobutylene、Cis-2-Butene、Iso-Pentane、N-Pentane、1.3-Butadiene、N-Hexane、O2、N2、methane、H2S、CO、CO2、Ar、1-Pentene、Trans-2-Pentene、Cis-2-Pentene、2-Methyl-2-Butene、1-Butyne、Vinyl Acetylene、H2（concentration shall be based on demand） |
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Determination of hydrocarbon impurities in butadiene |
BW(DT0103) |
Calibration liquid：propane、Propylene、Isobutane、n-butane、Propadiene、Acetylene、Trans-2-Butene、Isobutylene、1-butene、Cis-2-Butene、Iso-Pentane、N-Pentane、1.2-Butadiene、Propyne、1-Butyne and Vinyl Acetylene in butadiene |
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Determination of trace dimer in butadiene |
BW(DT0103) |
Calibration liquid：4-Vinyl-1-Cyclohexene in N-Hexane or或N-Heptane |
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Determination of oxygen in gaseous phase above liquid butadiene |
N2 bal.：BW(DT0159) |
Calibration gas：O2 in N2 or Ar 50ml/m³~5000ml/m³ |
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Determination of hydrocarbon impurities in 1-butene |
BW(DT0103) |
Calibration liquid：propane、Propylene、isobutane、nbutane、Propadiene、Acetylene、Trans-2-Butene、Isobutylene、Cis-2-Butene and 1.3-Butadiene、丙炔 in 1-butene |
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Determination of trace Propadiene and Propyne in 1-butene |
Calibration liquid：Propadiene and Propyne in 1-butene |
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Determination of Methanol and Tert-Butyl Methyl Ether in 1-butene |
BW(DT0103) |
Calibration liquid：Methanol and Tert-Butyl Methyl Ether in 1-butene |
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Determination of hydrocarbon impurities in Isobutylene |
BW(DT0103) |
Calibration liquid：propane、propylene、isobutane、n-butane、Trans-2-Butene、1-butene、Cis-2-Butene、Propyne and 1.3-Butadiene in Isobutylene |
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Determination of oxy-compounds in Isobutylene |
BW(DT0103) |
Calibration liquid：Dimethyl Ether、Tert-Butyl Methyl Ether、Methanol、Ethanol、Isopropanol、Tert-Butanol、Sec-Butanol、2-Methyl-1-Propanol、1-Butanol、Acetone in Isobutylene |
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Determination of dimer in Isobutylene |
BW(DT0103) |
Calibration liquid： 2.4.4-Trimethyl-1-Pentene、2.4.4-Trimethyl-2-Pentene in N-Pentane |
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Determination of trace sulfur in light olefins |
BW(DT0103) |
Calibration liquid：Dibutyl Sulfide or Thiophene in Isobutylene、2.2.4-Trimethylpentane or N-Heptane |
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Calibration liquid for Pyrolysis C4 |
BW(DT)0103 |
Mixed liquid with isobutane、nbutane、Trans-2-Butene、1-Butene、Isobutylene、Cis-2-Butene、1.3-Butadiene、1.2-Butadiene、1-Butyne、VA、N-Pentane、Iso-Pentane、11-Pentene、Cyclopentane、Isoprene、3-Methyl-1-Butene，concentration can be designed as demand。（with liquid tule in N2 pad 2MPa） |
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Chloride Calibration gas |
BW(DT)0127 |
Vinyl Chloride、Chloroethane、Methyl Chloride、Allyl Chloride、Dichloromethane、1.2-Dichloroethane in N2 or CH4 balance concentration 1～100（umol/mol） |
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composition analysis of natural gas |
BW(DT)0142 |
He，H2，O2，N2，CO2，ethane，propane，，n-butane，Neopentane，Iso-Pentane，N-Pentane，N-Hexane，N-Heptane and N-Octane，concentration 0.01%～100%（mol/mol）, compositions and concentration can be designed as demand |
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LPG |
BW(DT)0137 |
methane、ethane、propylene、propane、cyclopropane、Propylene、isobutane、n-butane、Propadiene、Acetylene、Trans-2-Butene、n-butene、iso-butene、cis-2--butene、Iso-Pentane、N-Pentane、1.3-Butadiene、Propyne、N-Hexane，concentration 0.01%～30%（mol/mol），compositions and concentration can be designed as demand. |
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Ethylene Glycol circulating gas |
BW(DT)0152 |
MN、CO、NO、N2、DMC、CH4O、MF、CO2、N2O、CH4 compositions and concentration can be designed as demand. |
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DMC calibration liquid |
BW(DT)0117 |
DMC、CH4O、MF、DMO compositions and concentration can be designed as demand. |
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DMO calibration liquid |
BW(DT)0131 |
MN、DMO、DMC、CH4O、MF、ML compositions and concentration can be designed as demand. |
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Ethylene Glycol calibration liquid |
BW(DT)0131 |
Diethylene Glycol、1.4-Butanediol、1.2- Butanediol、1.2-Hexanediol、Ethylene carbonate、Propylene glycol、Triethylene glycol、2-Hydroxymethyl-1.3-Dioxolane、Methyl glycolate、Ethylene Glycol balance，compositions and concentration can be designed as demand. |
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Methanol calibration liquid |
BW(DT)0131 |
H2O、Ethanol、Acetonitrile、Isopropanol、2-Methyl-1-Propanol、Acetone、Methyl Acetate in Methanol balance, compositions and concentration can be designed as demand |
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Determination of impurities in benzene |
BW(DT0109) |
Calibration liquid：toluene、Ethylbenzene、Cyclohexane、1.4-Dioxane、N-Nonane in benzene（compositions and concentration can be designed as demand.） |
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BW(DT0109) |
Calibration liquid: Dimethylpentane、Cyclohexane、N-Heptane、Methylcyclopentane、Methylcyclohexane、N-Nonane、thiophene、toluene in benzene（compositions and concentration can be designed as demand.） |
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Determination of non-aromatic hydrocarbon in benzene |
BW(DT0109) |
Calibration liquid：isobutane、n-butane、1.3-Butadiene、Cis-2-Butene、N-Pentane、Iso-Pentane、N-Hexane in benzene （compositions and concentration can be designed as demand） |
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Determination of thiophene in benzene |
BW(DT0109) |
Calibration liquid: thiophene in benzene（0mg/kg~100mg/kg） |
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Determination of Sulfolane in benzene |
BW(DT0109) |
Calibration liquid：Sulfolane in benzene（compositions and concentration can be designed as demand） |
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Determination of CS2 in benzene |
Benzene bal: BW(DT0109) |
Calibration liquid：Carbon Disulfide in benzene/ toluene（compositions and concentration can be designed as demand） |
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Determination of hydrocarbon impurities in toluene |
BW(DT0104) |
Calibration liquid：N-Nonane、benzene、Decane、N-Hendecane、ethylbenzene、m-xylene、p-xylene、o-xylene in toluene（concentration can be designed as demand） |
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Determination of Sulfolane in toluene |
BW(DT0104) |
Calibration liquid：Sulfolane in toluene（concentration can be designed as demand） |
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Determination of hydrocarbon impurities in Ethylbenzene |
BW(DT0111) |
Calibration liquid：N-Nonane、benzene、toluene、o-cylene、N-Hendecane、p-xylene、m-xylene、Cumene、N-Propylbenzene、4-ethyltoluene、3-ethyltoluene、tert-butylbenzene、isobutylbenzene、sec-butylbenzene、styrene、2-ethyltoluene、m-diethylbenzene、p-diethylbenzene、butylbenzene、O-diethylbenzene in Ethylbenzene（concentration can be designed as demand） |
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Determination of organic chloride in Ethylbenzene |
Toluene bal.:BW(DT0104) |
Calibration liquid： 2,4,6-trichloropenol（if 2,4,6-trichloropenol，balance liquid shall be methanol）Chlorobenzene or in toluene/p-xylene/ethylbenzene/ Methanol/2.2.4-Trimethylpentane（concentration can be designed as demand） |
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Determination of hydrocarbon impurities in Styrene |
BW(DT0166) |
Calibration liquid：ethylbenzene、p-xylene、m-xylene、o-xylene、Cumene、N-Propylbenzene、3-ethyltoluene、4-ethyltoluene、2-phenyl-1-propene、phenylacetylene、3-methylstyrene、4-methylstyrene、toluene、heptane in Styrene（concentration can be designed as demand） |
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Determination of polymer in Styrene |
BW(DT0104) |
Calibration liquid：polystyrene in toluene（concentration can be designed as demand） |
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Determination of inhibitor content in Styrene |
BW(DT0104) |
Calibration liquid：4-tert-butylcatechol in toluene（concentration can be designed as demand） |
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Determination of hydrocarbon impurities in Cumene |
BW(DT0170) |
Calibration liquid： non-aromatic hydrocarbon 、benzene、toluene、Ethylbenzene、p-xylene、m-xylene、o-xylene、N-Propylbenzene、Tert-Butylbenzene、Sec-Butylbenzene、M-cymene、p-cymene、butylbenzene、α-methylstyrene、1.3-diisopropylbenzene、p-diisopropylbenzene、acetophenone、1-(4-methylpheny)ethanol、phenol in Cumene balance （concentration can be designed as demand） |
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Determination of phenol in cumene |
BW(DT0170) |
Calibration liquid：phenol in cumene balance（concentration can be designed as demand） |
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Determination of in phenolic compound and cumyl hydroperoxide in cumene |
BW(DT0131) |
Calibration liquid：Phenol、p-cresol、O-cresol、p-isopropylphenol、2-isopropylphenol、cumyl hydroperoxide in Methanol（concentration can be designed as demand） |
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Determination of hydrocarbon impurities in p-xylene |
BW(DT0112) |
Calibration liquid：N-Nonane、benzene、toluene、ethylbenzene、m-xylne、Cumene、o-xylene、1.4-Diethylbenzene in p-xylene（concentration can be designed as demand） |
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Sulfolane in water |
BW(DT)0179 |
Sulfolane in water （1-1000mg/kg） |
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hydrocarbon in Sulfolane |
BW(DT)0184 |
N-Heptane、benzene、toluene、ethylbenzene、xylene in Sulfolane balance (concentration can be designed as demand） |
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C5 mixture gas sample |
BW(DT)0103 |
2-butyne、1.3-Cyclopentadiene、3-Methyl-1-Butene、Iso-Pentane、1.3-Pentadiene、Isoprene、1-Pentene、1-hezene、N-Hexane、2-Methylpentane in N-Pentane balance (concentration can be designed as demand） |
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Sampling of hydrocarbon in cracking C5 |
BW(DT)0103 |
Isobutane、n-butane、3-Methyl-1-Butene、2-butyne、Iso-Pentane、1-Pentene、trans-2-pentene、cis-2-pentene、2-Methyl-2-Butene、Trans-1.3-Pentadiene、cis-1.3-Pentadiene、Cyclopentadiene、Cyclopentene、2-Methylpentane、Cyclopentane、Cyclohexane、benzene、N-Hexane、toluene in N-Pentane balance(concentration can be designed as demand） |
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cracking C9 mixture liquid |
BW(DT)0103 |
toluene、ethylbenzene、p-xylene、m-xylene、o-xylene、 2-Phenyl-1-Propene、m-Methylstyrene、p-Methylstyrene、o-Methylstyrene、dicycloopentadiene、Indene、Naphthalene、α-Methylnaphthalene、β- Methylnaphthalene、β—Methylstyrene in N-Nonane balance(concentration can be designed as demand） |
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Sampling of Acetonitrile purity and organic impurities |
BW(DT)0181 |
Acetone、Acrylonitrile、Propionitrile、Butanone、oxazole、allylalcohol、Pyridine、trans-crotononitrile、cis-crotononitrile in Acetonitrile balance(concentration can be designed as demand） |
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Benzene series in water |
BW(DT)0179 |
benzene、toluene、ethylbenzene、xylene、n-propylbrnzene in water balance（1-20mg/kg） |
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Determination of water in aromatic hydrocarbon |
BW(DT0181) |
Water in benzene, toluene(concentration can be designed as demand） |
Calibration Gas for Auxiliary Testing in Petrochemical Industry
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RM |
RM No. |
Composition of RM |
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Mixture liquid of Aromatics or aromatic and non-aromatic hydrocarbons |
BW(DT0109) |
benzene、toluene、ethylbenzene、o-xylene、M-xylene、p-xylene、cumene、N-Propylbenzene、3-ethyltoluene、2-ethyltoluene、4-ethyltoluene、а- Methylstyrene、Phenylacetylene、1.3-Diethylbenzene、1.4-Diethylbenzene、1.2-Diethylbenzene、Butylbenzene、1，2，4-triethylbenzene、1，3，5-triethylbenzene、Styrene、pentane、hexane、Heptane、octane、Nonane、Indan、Naphthalene、1-Methylnaphthalene、2-Methylnaphthalene (concentration can be designed as demand） |
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Calibration gas of C1~C6 hydrocarbon in N2 balance |
BW(DT0160) |
methane、ethylene、ethane、propylene、propane、Propadiene、N-Butene、n-butane、iso-butane、Isobutylene、Propyne、trans-2-butene、cis-2-butene、1-Hexene、hexane、N-Pentane、Iso-Pentane in N2 balance (concentration can be designed as demand） |
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Calibration gas of H2, O, N2, Co, CO2, H2S and hydrocarbons |
BW(DT0130 ) |
H2、O2、CO、CO2、CH4、ethane、ethylene、Acetylene、propane、propylene、Propadiene、Propyne、Cyclopropane、iso-butane、n-butane、Trans-2-Butene、1-Butene、Isobutylene、cis-2-Butene、1.3-Butadiene、1.2-Butadiene、Propyne、Vinyl Acetylene、ethylene、Iso-Pentane、N-Pentane、1-Pentene、Cis-2-Pentene、Trans-2-Pentene、2-Methyl-2-Butene、hexane、H2S in N2 balance（(concentration can be designed as demand） |
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Mixture liquid of hydrocarbons |
BW(DT0103) |
ethane、ethylene、Acetylene、propane、propylene、Propyne、Cyclopropane、Propadiene、n-butane、iso-butane、N-Butene、Isobutylene、trans-2-butene、cis-2-butene、1.3-Butadiene、1.2-Butadiene、1-Butyne、Propyne、Vinyl Acetylene、ethylene、N-Pentane、iso-Pentane、Cyclopentane、Cis-2-Pentene、trans-2-Pentene、1-Pentene、N-Hexane (concentration can be designed as demand） |
Calibration Gas for Environmental Monitoring in Petrochemical Industry
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RM |
RM No. |
Composition |
Relative |
Appliable standard |
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RM of CO in Air |
GBW(E)062250 |
5.00 ~499(μmol/mol) |
2%(k=2) |
GB/T 18204.2-2014 Examination methods for public places-part 2: chemical pollutants |
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500~50000(μmol/mol) |
1%(k=2) |
GB 9801-88 Air quality-Determination of carbon monoxide- Non-dispersive infrared spectrometry |
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HJ 965-2018 Ambient air-Automatic determination of carbon monoxide -Non-dispersive infrared spectrometry method |
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Calibration sample of Determination of Ethylene Oxide in Air |
BW(DT0128) |
1.00~4999.9(μmol/mol) |
2%(k=2) |
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RM of Benzene in Air |
GBW(E)062243 |
0.02~0.0999(μmol/mol) |
10%(k=2) |
GB/T 18204.2-2014 Examination methods for public places-part 2: chemical pollutants |
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0.100~0.999(μmol/mol) |
3%(k=2) |
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1.00~49.9（μmol/mol） |
2%(k=2) |
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50.0~999（μmol/mol） |
1%(k=2) |
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RM of CH4 in Air |
GBW(E)060678 |
1.00~4999.9(μmol/mol) |
2%(k=2) |
HJ 1012-2018 Ambient air and stationary source emission -specifications and test procedures for hydrocarbons, methane and nonmethane hydrocarbons portable total monitoring instrument. |
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5000~30000 (μmol/mol) |
1%(k=2) |
HJ 1013-2018 specifications and test procedures for nonmethane hydrocarbons continuous emission monitoring system in stationary sources |
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HJ 38-2017 Stationary source emission-determination of total hydrocarbons, methane and nonmethane hydrocarbons-Gas chromatography |
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HJ 604-2017 Ambient air-determination of total hydrocarbons, methane and nonmethane hydrocarbons-direct injection/Gas chromatography |
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RM of Iso-butane in Air |
GBW(E)061049 |
0.18%~1.44% |
2%(k=2) |
JJG 693-2011 Alarmer detectors of combustible gas |
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RM of O2 in N2 |
GBW(E)062593 |
5%~30% |
1%（k=3） |
J JJG 365-2009 Electrochemical Oxygen Meter |
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H2S in N2(Air) |
GBW(E)062156 |
1.00~3000(μmol/mol) |
2% (k=3) |
JJG 695-2003-Sulfur Hydrogen Gas detectors MT 1084 2008 Coal mine hydrogen sulfide alarm detector GB/T 14678-93 Air quality-Determination of sulfuretted hydrogen, methyl sulfhydryl, dimethyl sulfide and dimethyl disulfide -Gas chromatography |
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RM of Propane in Air |
GBW(E)062248 |
1.00~100(μmol/mol) |
2%(k=2) |
HJ 1013-2018 specifications and test procedures for nonmethane hydrocarbons continuous emission monitoring system in stationary sources |
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100~10000(μmol/mol) |
1%(k=2) |
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RM of Propane in N2 |
GBW(E)062249 |
1.00~100(μmol/mol) |
2%(k=2) |
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100~10000(μmol/mol) |
1%(k=2) |
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RM of Isobutene in N2 |
GBW(E)062583 |
1.00~499(μmol/mol) |
2%（k=2） |
JJG（yue）035-2017 Benzene Gas Detectors |
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GBW(E)062584 |
500~10000(μmol/mol) |
1%（k=2） |
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RM of CO2 in N2 |
GBW(E)062587 |
2.00~499(μmol/mol) |
2%(k=2) |
GB/T 18204.2-2014 Examination methods for public places-Part 2: chemical pollutants |
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GBW(E)062588 |
500~10000(μmol/mol) |
1%(k=2) |
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RM of CO2 in Air |
GBW(E)062589 |
2.00~499(μmol/mol) |
2%(k=2) |
HJ 870-2017 Stationary source emission-Determination of carbon dioxide -Non-dispersive infrared absorption method |
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GBW(E)062590 |
500~10000(μmol/mol) |
1%(k=2) |
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Determination of Acetonitrile in water |
BW(DT0179) |
Acetonitrile in water |
— |
HJ 789-2016 Water quality-Determination of Acetonitrile Direct injection/Gas chromatograph |
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Benzene in Water |
BW(DT0179) |
Benzene in water |
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